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1

Mechanisms of elimination and substitution reactions. Spontaneous solvolysis reactions via carbanion and carbocation intermediates

Qingshui Meng, Baoan Du, Alf Thibblin

Journal:

Journal of Physical Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 78 KB

english, 1999

2

Measurement of high pulsed microwave power in free space

Dagys, M., Kancleris, Z., Orsevskij, V., Simniskis, R., Backstrom, M., Thibblin, U., Wahlgren, B.

Journal:

IEEE Transactions on Microwave Theory and Techniques

Year:

1995

Language:

english

File:

PDF, 212 KB

english, 1995

3

Reaction branching and extreme kinetic isotope effects in the study of reaction mechanisms

Thibblin, Alf, Ahlberg, Per

Journal:

Chemical Society Reviews

Year:

1989

Language:

english

File:

PDF, 835 KB

english, 1989

4

Functional-integral approach to the bound magnetic polaron in semimagnetic semiconductors

Micnas, R., Thibblin, U., Chao, K. A.

Journal:

Physical Review B

Year:

1988

Language:

english

File:

PDF, 305 KB

english, 1988

5

[IEEE 23rd European Microwave Conference, 1993 - Madrid, Spain (1993.10.4-1993.10.6)] 23rd European Microwave Conference, 1993 - Microwave pulsed high power measurement in a free space making use of resistive sensors

Dagys, M., Kancleris, Z., Simniskis, R., Backstrom, M., Thibblin, U., Wahlgren, B.

Year:

1993

Language:

english

File:

PDF, 2.49 MB

english, 1993

6

A Conceptual Approach to Teaching Mathematics to Students With Intellectual Disability

Göransson, Kerstin, Hellblom-Thibblin, Tina, Axdorph, Eva

Journal:

Scandinavian Journal of Educational Research

Year:

2016

Language:

english

File:

PDF, 377 KB

english, 2016

7

Biopsychosocial model and the ICF-CY in in-service training: general educators’ reflections

Hellblom-Thibblin, T, Klang, N, Åman, K

Journal:

International Journal of Developmental Disabilities

Year:

2012

Language:

english

File:

PDF, 244 KB

english, 2012

8

Influence of microstructure on thermal cycling lifetime and thermal insulation properties of yttria-stabilized zirconia thermal barrier coatings for diesel engine applications

Thibblin, Anders, Jonsson, Stefan, Olofsson, Ulf

Journal:

Surface and Coatings Technology

Year:

2018

Language:

english

File:

PDF, 3.11 MB

english, 2018

9

Oxygen-Base-Catalyzed 1,3-Proton Transfer Competing with 1,2-Elimination. Evidence of A Common Tightly Hydrogen-Bonded Intermediate

Alf Thibblin, Per Ahlberg

Journal:

Bulletin des Sociétés Chimiques Belges

Year:

1982

Language:

english

File:

PDF, 39 KB

english, 1982

10

Microcalorimetry as a Tool in Mechanistic Studies of Organic Reactions.

Journal:

Year:

2002

File:

PDF, 23 KB

2002

11

Microcalorimetry as a tool in mechanistic studies of organic reactions

Journal:

Journal of Physical Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 159 KB

english, 2002

12

Reaction branching as a mechanistic alternative to tunneling in explaining anomalous temperature-dependencies of kinetic isotope effects

Journal:

Journal of Physical Organic Chemistry

Year:

1988

Language:

english

File:

PDF, 334 KB

english, 1988

13

Ion pairs in solvolysis reactions. Kinetic deuterium isotope effects for deprotonation of carbocation intermediates in aqueous solvent

Journal:

Journal of Physical Organic Chemistry

Year:

1989

Language:

english

File:

PDF, 640 KB

english, 1989

14

Solvolysis of 1,1-diphenylethyl derivatives in highly aqueous media. Reaction via ion pairs

Journal:

Journal of Physical Organic Chemistry

Year:

1992

Language:

english

File:

PDF, 386 KB

english, 1992

15

Acid-catalysed solvolysis of optically active 1-Phenyl-1-methoxythane. The role of ion– molecule pair intermediates

Journal:

Journal of Physical Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 367 KB

english, 1993

16

Ion–molecule pairs as intermediates in solvolysis. Catalysis by the pyridine leaving group on the elimination reaction

Alf Thibblin, Harvinder Sidhu

Journal:

Journal of Physical Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 175 KB

english, 1993

17

Competing solvolytic substitution and elimination reactions via a common irreversibly formed ion–molecule pair intermediate

Harvinder Sidhu, Alf Thibblin

Journal:

Journal of Physical Organic Chemistry

Year:

1994

Language:

english

File:

PDF, 572 KB

english, 1994

18

Unusually large kinetic deuterium isotope effects on oxidation reactions. 1. The mechanism of hydroxide-catalysed permanganate oxidation of PhCD(CF3)OH and PhCD(CH3)OH in Water

Journal:

Journal of Physical Organic Chemistry

Year:

1995

Language:

english

File:

PDF, 398 KB

english, 1995

19

ChemInform Abstract: Solvent-Promoted E2 Reaction Competing with SN2 Reaction and Stepwise Solvolytic Elimination and Substitution Reactions

Q. MENG, A. THIBBLIN

Journal:

Year:

1996

File:

PDF, 28 KB

1996

20

Is Benzene Oxide Homoaromatic? A Microcalorimetric Study †

Jia, Zhi Sheng, Brandt, Peter, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

2001

Language:

english

File:

PDF, 75 KB

english, 2001

21

Borderline between E1 and E2 mechanisms. Bimolecular base-promoted elimination via ion pairs competing with concerted E2 elimination

Journal:

Journal of the American Chemical Society

Year:

1989

Language:

english

File:

PDF, 669 KB

english, 1989

22

Mechanisms of Solvent- and Base-Promoted Imine-Forming Elimination Reactions

Meng, Qingshui, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

1997

Language:

english

File:

PDF, 166 KB

english, 1997

23

Theory of bound magnetic polarons in diluted magnetic semiconductors

Thibblin, U, Micnas, R, Chao, K A

Journal:

Journal of Physics Condensed Matter

Year:

1989

Language:

english

File:

PDF, 759 KB

english, 1989

24

Borderline Solvolytic Reactions. Appearance of Solvent-Promoted E2 Reaction in Competition with Stepwise Elimination and Substitution Reactions

Meng, Qingshui, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

1995

Language:

english

File:

PDF, 191 KB

english, 1995

25

The role of ion-molecule pair intermediates in acid-catalyzed solvolysis. General base-catalyzed formation of 4-methylbenzyl carbocation and its trapping by nucleophiles

Journal:

Journal of Organic Chemistry

Year:

1993

Language:

english

File:

PDF, 806 KB

english, 1993

26

Kinetic and Thermodynamic Stability of Naphthalene Oxide and Related Compounds. A Comparative Microcalorimetric and Computational (DFT) Study

Brandt, Peter, Jia, Zhi Sheng, Thibblin, Alf

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 130 KB

english, 2002

27

Competing base-promoted E2 and E1 reactions of an acidic tertiary substrateElectronic supplementary information (ESI) available: the effect of base concentration on rate constant and product composition. See http://www.rsc.org/suppdata/p2/b2/b200758d/

Zeng, Xiaofeng, Thibblin, Alf

Journal:

Journal of the Chemical Society Perkin Transactions 2

Year:

2002

Language:

english

File:

PDF, 172 KB

english, 2002

28

Incorporation of a Triglutamyl Spacer Improves the Biodistribution of Synthetic Affibody Molecules Radiofluorinated at the N-Terminus via Oxime Formation with 18 F-4-Fluorobenzaldehyde

Rosik, Daniel, Thibblin, Alf, Antoni, Gunnar, Honarvar, Hadis, Strand, Joanna, Selvaraju, Ram Kumar, Altai, Mohamed, Orlova, Anna, Eriksson Karlström, Amelie, Tolmachev, Vladimir

Journal:

Bioconjugate Chemistry

Year:

2014

Language:

english

File:

PDF, 2.03 MB

english, 2014

29

Deprotonation of ions pairs in aqueous solvent. Competing bimolecular and solvolytic elimination reactions

Journal:

Journal of the American Chemical Society

Year:

1987

Language:

english

File:

PDF, 704 KB

english, 1987

30

Acid-Catalyzed Solvolysis of Allylic Ethers and Alcohols. Competing Elimination and Substitution via a Thermodynamically “Stable” Carbocation †

Pirinccioglu, Necmettin, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

1998

Language:

english

File:

PDF, 75 KB

english, 1998

31

Ion-pair intermediates and extreme deuterium isotope effects in partially diastereospecific base-promoted elimination competing with base-catalyzed 1,3-proton transfer

Thibblin, Alf, Ahlberg, Per

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 939 KB

english, 1979

32

Discovery and Development of 11C-Lu AE92686 as a Radioligand for PET Imaging of Phosphodiesterase10A in the Brain

Kehler, J., Kilburn, J. P., Estrada, S., Christensen, S. R., Wall, A., Thibblin, A., Lubberink, M., Bundgaard, C., Brennum, L. T., Steiniger-Brach, B., Christoffersen, C. T., Timmermann, S., Kreilgaar

Journal:

Journal of Nuclear Medicine

Year:

2014

Language:

english

File:

PDF, 898 KB

english, 2014

33

Stepwise and Concerted Solvolytic Elimination and Substitution Reactions: E1 Reaction via a Primary Carbocation

Meng, Qingshui, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

1997

Language:

english

File:

PDF, 189 KB

english, 1997

34

Solvent-Promoted E2 Reaction Competing with SN2 Reaction and Stepwise Solvolytic Elimination and Substitution Reactions

Meng, Qingshui, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

1995

Language:

english

File:

PDF, 1.13 MB

english, 1995

35

Borderline between E1cB and E2 mechanisms. Elimination of hydrogen chloride from fluorene derivatives

Journal:

Journal of the American Chemical Society

Year:

1988

Language:

english

File:

PDF, 668 KB

english, 1988

36

Unstable carbanions. General acid catalysis of the cleavage of 1-phenylcyclopropanol and 1-phenyl-2-arylcyclopropanol anions

Thibblin, Alf, Jencks, William P.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.33 MB

english, 1979

37

Stepwise base-promoted elimination of hydrochloric acid via hydrogen-bonded carbanions studied by reaction branching and extreme deuterium isotope effects. Parallel carbocationic and carbanionic reactions

Oelwegaard, Maria, McEwen, Ian, Thibblin, Alf, Ahlberg, Per

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 779 KB

english, 1985

38

Enlarged deuterium isotope effects in oxyanion-catalyzed 1,3 proton transfer competing with 1,2 elimination as a probe of a common tightly hydrogen-bonded intermediate

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 738 KB

english, 1983

39

Borderline between E1cB and E2 Mechanisms. Chlorine Isotope Effects in Base-Promoted Elimination Reactions

Jia, Zhi Sheng, Rudziński, Juliusz, Paneth, Piotr, Thibblin, Alf

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 58 KB

english, 2002

40

Leaving-group effects and ion-pair intermediates in base-promoted elimination competing with base-catalyzed 1,3-proton transfer

Thibblin, Alf, Ahlberg, Per

Journal:

Journal of the American Chemical Society

Year:

1977

Language:

english

File:

PDF, 572 KB

english, 1977

41

The Role of Ion−Molecule Pairs in Solvolysis Reactions. Nucleophilic Addition of Water to a Tertiary Allylic Carbocation

Jia, Zhi Sheng, Ottosson, Henrik, Zeng, Xiaofeng, Thibblin, Alf

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 73 KB

english, 2002

42

Electrostatic stabilization of the transition state in proton transfer from carbon

Journal:

Journal of the American Chemical Society

Year:

1984

Language:

english

File:

PDF, 513 KB

english, 1984

43

Kinetic deuterium isotope effects as evidence for a common ion-pair intermediate in solvolytic elimination and substitution reactions of 1,1-diphenylethyl chloride

Thibblin, Alf, Sidhu, Harvinder

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 678 KB

english, 1992

44

Ion−Molecule Pairs in Leaving-Group-Promoted Solvolytic Elimination Reactions

Thibblin, Alf, Saeki, Yoshihiro

Journal:

Journal of Organic Chemistry

Year:

1997

Language:

english

File:

PDF, 120 KB

english, 1997

45

Concerted and Stepwise Solvolytic Elimination and Substitution Reactions: Stereochemistry and Substituent Effects

Meng, Qingshui, Gogoll, Adolf, Thibblin, Alf

Journal:

Journal of the American Chemical Society

Year:

1997

Language:

english

File:

PDF, 213 KB

english, 1997

46

Mechanisms of solvolytic elimination reactions of tertiary substrates: stereospecific 1,2-elimination reactions

Meng, Qingshui, Thibblin, Alf

Journal:

Journal of the Chemical Society Perkin Transactions 2

Year:

1999

Language:

english

File:

PDF, 190 KB

english, 1999

47

Acid-catalysed aromatization of anthranyl derivatives. A kinetic and thermodynamic study

Pirinccioglu, Necmettin, Jia, Zhi Sheng, Thibblin, Alf

Journal:

Journal of the Chemical Society Perkin Transactions 2

Year:

2001

Language:

english

File:

PDF, 112 KB

english, 2001

48

Acid-catalysed intramolecular allylic rearrangement of methyl ethers in aqueous solvent. Evidence for the intermediacy of ion?molecule pairs in solvolysis

Journal:

Journal of the Chemical Society Perkin Transactions 2

Year:

1987

Language:

english

File:

PDF, 598 KB

english, 1987

49

Ion-molecule pairs in solvolysis. Trapping of an anthranyl carbocation molecule pair by solvent water

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1990

Language:

english

File:

PDF, 255 KB

english, 1990

50

Mechanism of elimination from a tightly hydrogen-bonded carbanion

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1984

Language:

english

File:

PDF, 204 KB

english, 1984